Treat coma and shock if they occur. Causes eye, skin, and respiratory tract irritation. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. /Formaldehyde/ /Formalin (as formaldehyde)/, NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. Formaldehyde (/ f ə r ˈ m æ l d ə h aɪ d / fer-mal-duh-hahyd, also / f ɔːr ˈ m æ l d ə h aɪ d / fawr-) (systematic name methanal) is a naturally occurring organic compound with the formula CH 2 O (H−CHO). Separated from incompatible materials. R34- Causes burns. Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus. Avoid breathing dust. If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc.FORMALDEHYDE (ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.) Acute -- below 1 ppm, odor perceptible to most. Solutions splashed in eyes have caused injuries ranging from severe, permanent corneal opacification and loss of vision to minor discomfort. Other biodegradation screening tests gave half-lives ranging from <1 to 17.3 days(7-12). It can cause irreversible eye damage in instances of severe overexposure. P321 Specific treatment (see ... on this label). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Handle in accordance with good industrial hygiene and safety practice. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. Fresh air, rest. Ingestion of solid or of a solution in water irritates mouth, throat, and stomach and may cause death. Turn off gas at source if possible. Evacuate area. 2 0 obj /Formaldehyde/ /Formalin (as formaldehyde)/. SAFETY DATA SHEET GHS product identifier Other means of identification Product type Section 1. Many liquids are lighter than water. Vapors may form explosive mixtures with air. Formaldehyde: off-gas : 200-001-8: Section 3 - Hazards Identification EMERGENCY OVERVIEW. 5.2. Use water to keep fire exposed containers cool. endobj High formaldehyde concentration or methanol content lowers flash point. But few homes are now insulated with UFFI. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. Use personal protective equipment. Flammable liquid when exposed to heat or flame; can react vigorously with oxidizers. Very reactive, combines readily with many substances, 40% solution is powerful reducing agent. 1B (H350) Concentration: < 5% Component: Methanol CAS No: 67-56-1 EC No: 200-659-6 Index No: 603-001 -00-x Registration No: 01-2119433307 -44-xxxx Classification: Flam. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Experiments performed on a variety of fish and shrimp showed no bioconcentration of formaldehyde(4,5). SECTION 2 — HAZARDS IDENTIFICATION. Inhalation. Formaldehyde resins are used as adhesives and binders in many different industries that produce wood products, pulp and paper, synthetic fibres, plastics and coating and textiles. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. Automobile exhaust is a major source of formaldehyde in outdoor air. Identification GHS Product FORMALDEHYDE SOLUTION 37 w/w, stablized with 10-12% methanol Identifier Company Name CHEM-SUPPLY PTY LTD (ABN 19 008 264 211) 38 - 50 Bedford Street GILLMAN SA 5013 Australia Address Tel: (08) 8440-2000 Fax: (08) 8440-2001 Telephone/Fax … P261 Avoid breathing dust/fume/gas/mist/vapours/spray. Also, a positive association has been observed between exposure to formaldehyde and sinonasal cancer. Commercial formaldehyde-alcohol solutions are stable. The PCBU must also obtain a copy of the safety data sheet and make it readil… Refer immediately for medical attention. 1.3. GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name Formaldehyde solution, 36.5: -38% Product Number : F8775 Brand : Sigma Index-No. Synonym :Monoxide; Flue gas; Carbon oxide; carbonic oxide; Monoxide of carbon; Carbon monooxide SDS # :001014 Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone :1-866-734-3438 Section 2. P271 Use only outdoors or in a well-ventilated area. However, possible confounding factors were not evaluated in this study. Rinse skin with plenty of water or shower. : 605-001-00-5 REACH No. may react violently with strong oxidizing agents (hydrogen peroxide, performic acid, perchloric acid in the presence of aniline, potassium permanganate, nitromethane). A study of hospital equipment sterilizing workers did not report an association between formaldehyde exposure and increased spontaneous abortions. Prevent firefighting water entering watercourses or ground-water. Runoff to sewer may create fire or explosion hazard. According to a classification scheme(3), this estimated Koc value suggests that formaldehyde is expected to have very high mobility in soil(SRC). MAJOR HEALTH HAZARDS:potentially fatal if inhaled, harmful on contact with the skin or swallowed, respiratory tract burns, skin burns, eye burns, allergic reactions, cancer hazard (in humans) Higher concentrations or splashes may cause irreversible eye damage. Rinse mouth. Using OECD Guide-line 301D (Ready Biodegradability: Closed Bottle Test), formaldehyde achieved 90% in 28 days using non-acclimated inoculum which classified the compound as readily biodegradable(2). Absorb with DRY earth or non-combustible material. Formaldehyde Solution Flinn Scientific, Inc. P.O. Use fluorocarbon water spray, Cellosize and Hycar to diminish vapors. There is sufficient evidence in experimental animals for the carcinogenicity of formaldehyde. 4-5 ppm, increased discomfort, mild lacrimation. Harmful if inhaled. purest form, formaldehyde is a colorless, highly toxic and flammable gas with the chemical formula HCHO or CH 2 O. Formalin solutions typically use up to 15% methanol as a stabilizer. (USCG, 1999). /From table/. Carc. 10 ppm, profuse lacrimation; can be withstood only for few minutes. Rinse skin with water [or shower]. Contact causes white discoloration, smarting, cra cking and scaling. A person conducting a business or undertaking (PCBU) must correctly labelhazardous chemicals used, handled or stored at the workplace, including containers and pipework. Flammable solid. Emergency and supportive measures: 1. It has virtually no activity for ethanol oxidation, but exhibits high activity for oxidation of long-chain primary alcohols and for oxidation of S-hydroxymethyl-glutathione, a spontaneous adduct between formaldehyde and glutathione. <> Liq. formaldehyde and carbon oxides). Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. View product specific information, MSDS, References and Buying FAQ. Also reacts violently with perchloric acid-aniline, performic acid, nitromethane, magnesium carbonate, and hydrogen peroxide. Refer immediately for medical attention. Incompatible with liquid oxygen. Formaldehyde is produced in large quantities industrially. The Koc of formaldehyde is estimated as 8(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). It is made of 37% formaldehyde and impurities such as methanol, small amounts of formic acid, aldehydes and ketones. <>>> Formaldehyde causes cancer of the nasopharynx and leukaemia. Reacts with nitrogen oxides at about 180; the reaction becomes explosive. On standing, especially in the cold, may become cloudy, and on exposure to very low temperature ppt of trioxymethylene formed; in air it slowly oxidizes to formic acid /40% solution/. Nearly colorless gas [Note: Often used in an aqueous solution]. It is used as a denaturant in formaldehyde-agarose gel electrophoresis of RNA. 3 0 obj Formaldehyde –urea resin is used as an insulating material in building construction. Will polymerize violently in the presence of caustics and nitrides; (amines) exothermic reaction, (Azo compound) exothermic reaction giving off nitrogen gas, (caustics) heat generation and violent polymerization, (dithiocarbamates) formation of flammable gases and toxic fumes, formation of carbon disulfide may result, (alkali and alkaline earth metals) heat generation and formation of a flammable hydrogen gas. Formaldehyde in aqueous effluent was degraded by activated sludge and sewage in 48-72 hr(3-6). Recommended Exposure Limit: 10 Hour Time-Weighted Average: 0.016 ppm. Safety Data Sheet Sodium Formaldehyde Bisulphite Solution SDS 26/7 Page n. 3 of 8 None in particular. endobj According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). E-mail (competent person) SDS@vwr.com 1.4 Emergency phone number Telephone +44 (0) 1270 502894 (CareChem24) 2 / 14 SECTION 2: Hazard identification 2.1 Classification of the substance or mixture 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP] Hazard classes and hazard categories Hazard statements Acute toxicity, category 3, oral, dermal and inhalation … Half-upright position. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Component: Formaldehyde CAS No: 50-00-0 EC No: 200-001-8 Index No: 605-001 -00-5 Classification: Acute Tox. Compound will polymerize with active organic materials such as phenol. 3 (H301 + H311 + H331), Skin Corr. %PDF-1.5 Formaldehyde exposure can also happen in offices and newly constructed homes via off-gas from wood products, paints and finishes, and cigarette smoke. Gas is stable in absence of water. stream 2. T - Toxic. Flash Point: 70 deg C. Warning! Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. (ERG, 2016), Toxic vapors such as carbon dioxide and carbon monoxide are generated during combustion. Rinse with plenty of water (remove contact lenses if easily possible). Ingestion. FIREFIGHTING MEASURES 5.1 Fire & Explosion Hazards: Will not burn, but high heat, may release formaldehyde gas which will increase the health hazards. 5.3. 10-20 ppm, breathing difficult, cough, severe burning of nose and throat. Some may be transported hot. Avoid contact with skin and eyes. Formaldehyde may also be used under restriction in the EUas a preservative in cosmetics and nail hardening products. Fireproof. a. Product identifier . Minimum storage temperature to prevent polymerization range from 83 deg F for 37% formaldehyde containing 0.05% methyl alcohol to 29 deg F for formaldehyde containing 15% methyl alcohol. 50-100 ppm, acute irritation of respiratory tract, very serious injury likely. Formaldehyde Formaldehyde (HCHO) CAS 50-00-0; UN 1198, UN 2209 (formalin) ... • Formaldehyde is a colorless, highly toxic, and flammable gas at room temperature that is slightly heavier than air. Show this safety data sheet to the doctor in attendance. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Containers may explode when heated. Manufacturers and importers of formaldehyde/formalin need to ensure that hazardous chemicals are labelled and that safety data sheets are prepared and provided. Suspected carcinogen. !#™kîºðp ×]„‘‰åÚt!Ô²#¡óݬ¡eºh­¼íF¨¥ìHh|•°-Bž³ÄEæ1‰¬ú«7\Æ(§’¥½¯ c“‹DÖӋu–­ï.©}ŽÒ{.˜œ'Vç. Acute exposure to formaldehyde can have a corrosive effect on the respiratory tract, gastrointestinal system, and skin. Reacts with nitrogen oxides at about 180; the reaction becomes explosive. (USCG, 1999). Gloves must be inspected prior to use. 3 Xi - Irritant. P302+P352 IF ON SKIN: Wash with plenty of water/... P312 Call a POISON CENTER/doctor/\u2026if you feel unwell. Vapors may travel to source of ignition and flash back. Remove contact lenses, if present and easy to do. High formaldehyde concentration or methanol content lowers flash point. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9804 Signal Word DANGER. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Developmental effects, such as birth defects, have not been observed in animal studies with formaldehyde. (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: May cause toxic effects if inhaled or ingested/swallowed. Particularly relevant to the discussions regarding sufficient evidence was a recent study accepted for publication which, for the first time, reported aneuploidy in blood of exposed workers characteristic of myeloid leukaemia and myelodysplastic syndromes, with supporting information suggesting a decrease in the major circulating blood-cell types and in circulating haematological precursor cells. Avoid dust formation. (ERG, 2016), Vapor or dust irritates eyes, mucous membranes, and skin; may cause dermatitis. For industry use only. These reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). DOWNLOAD MSDS (PDF) | Search MSDS currently available for download bioWORLD offers Formaldehyde (4%) in PBS for your research at low price. Polymerization reaction with phenol may develop sudden destructive pressure [Bretherick, 5th ed., 1995, p.168]. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. P272 Contaminated work clothing should not be allowed out of the workplace. Odour Threshold: 0,05 – 0,125 ppm (Formaldehyde) pH: 2,8 – 4,0 at 20°C Melting point: < -15°C Boiling point/boiling range: 93-96°C at 1.013 hPa Flash point: 62°C Method: c.c Evaporation rate: No information available Flammability (solid, gas): No information available Wash and dry hands. Ensure adequate ventilation. Skin -- primary irritation from strong solutions, gas. It also has minor uses in agriculture, as an analytical reagent, in concrete and plaster additives, cosmetics, disinfectants, fumigants, photography, and wood preservation. SARA Title III: Section 313 (Specific toxic chemical listings): 50-00-0 formaldehyde, 67-56-1 Methyl Alcohol RCRA: ND TSCA: All ingredients are listed. Remove all ignition sources. Ventilate closed spaces before entering them. SDS complies with OSHA’s Hazard Communication Rule 29, CFR 1910.1200. 2 (H225); … Fire will produce irritating, corrosive and/or toxic gases. CERCLA: Formaldehyde 50-00-0: RQ = 100 lbs (45.4 Kg). 77, No. Reacts with peroxide, nitrogen oxide, and performic acid causing explosions. (EPA, 1998), Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]: Flammable/combustible material. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/\u2026. FORMALDEHYDE 37-40% W/V LRG Protective actions during firefighting Avoid breathing fire gases or vapours. 1.1. Avoid fluid overload in patients with inhalation exposure because of the risk of pulmonary edema. (ERG, 2016), Behavior in Fire: Changes to formaldehyde gas, which is highly flammable. Recommended use and restrictions on use . Consult a physician. R40- Limited evidence of a carcinogenic effect. State Regulations. California … 4 0 obj Use water spray, dry chemical, alcohol foam, or carbon dioxide. An estimated BCF of 3 was calculated for formaldehyde(SRC), using a log Kow of 0.35(1) and a regression-derived equation(2). Seek medical attention if you feel unwell. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. Advice for firefighters Use suitable breathing apparatus. Maintain open airway and assist ventilation if necessary. Nonflammable Gas Mixture: Formaldehyde 1ppb-999ppm / Nitrogen 99.9001-99.9999% Not available. Formaldehyde, Lab Grade Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com SECTION 1: Identification of the substance/mixture and of the supplier Product name: Formaldehyde, Lab Grade Manufacturer/Supplier Trade name: Manufacturer/Supplier Article number: S25329 Recommended uses of the product and restrictions on use: Manufacturer Details: … .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, H314 Causes severe skin burns and eye damage, H341 Suspected of causing genetic defects. Product may generate formaldehyde which can … Exposure Routes: inhalation, skin and/or eye contact Symptoms: Irritation eyes, nose, throat, respiratory system; lacrimation (discharge of tears); cough; wheezing; [potential occupational carcinogen] Target Organs: Eyes, respiratory system (NIOSH, 2016), The probable oral lethal dose for humans is 0.5-5 g/kg, or between 1 ounce and 1 pint for a 150 pound person. Handle with gloves. The main products of decomposition are carbon monoxide and hydrogen. The Working Group was not in full agreement on the evaluation of formaldehyde causing leukaemias in humans, with a small majority viewing the evidence as sufficient of carcinogenicity and the minority viewing the evidence as limited. For precautions see section 2.2. In laboratories, the gas is more commonly dissolved in water and used as an aqueous solution called formalin. Administer supplemental oxygen, and observe for at least 4 to 6 hours. 1.2. Methanol 67-56-1 200-659-6 1.00 % v/v F - Highly flammable. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Very few human studies have been done on the adverse reproductive effects from exposure to Formaldehyde. Cat. The main products are carbon monoxide and hydrogen. P201 Obtain special instructions before use. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. 2-3 ppm, mild tingling of eyes. AEROBIC: Formaldehyde, present at 100 mg/L, reached 91% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test which classified the compound as readily biodegradable(1). P280 Wear protective gloves/protective clothing/eye protection/face protection. 1 0 obj During the 1970s, urea-formaldehyde foam insulation (UFFI) was used in many homes. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Consult an expert! Will burn if involved in a fire and give off noxious fumes (e.g. Homes in which UFFI was installed many years ago are not likely to have high formaldehyde levels now. Treat bronchospasm and pulmonary edema if they occur. Formaldehyde is used predominantly as a chemical intermediate. Formaldehyde, 37% w/w Safety Data Sheet according to Federal Register / Vol. The authors and Working Group felt that this study needed to be replicated. Vapour is heavier than air and is an explosion hazard. In addition, formaldehyde may interact with humic substances in soil(5) resulting in decreased mobility. Large Spill and Leak: Stop leak if it is safe to do so. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Formaldehyde is a severe skin irritant and sensitizer. Use of the substance/mixture : For laboratory and manufacturing us e only. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/15/2013 Revision date: 02/27/2014 Supersedes: 11/15/2013 Version: 1.1 03/05/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking . One of the most common uses of formaldehyde in the U.S is manufacturing urea-formaldehyde resins, used in particleboard products. endobj Materials containing formaldehyde can release it as a gas or vapor into the air. Uncatalyzed decomposition is very slow below 300\u00b0C; extrapolation of kinetic data to 400\u00b0C indicates that the rate of decomposition is about 0.44%/min at 101 kPa (1 atm). Continue rinsing. Studies produced a weak association (limited evidence) between adverse human female reproductive effects and occupational exposure. Avoid breathing vapours, mist or gas. R11- Highly flammable. Contact with substance may cause severe burns to skin and eyes. They can be exposed during the treatment of tex- tiles and the production of resins. Formaldehyde gas adsorbs on clay minerals to a degree at high gas concentrations which is an important quality in its use as a soil fumigant(4). For… Hazard class: Flammable liquids (Category 3). May be ignited by heat, sparks or flames. xœÍ[ÝsÓH§Šÿaí=2Ö|¨­­3¶ÙMH66µÅÁ>øŒ ¾Kbλpýu÷H¶dideñőåžéÏéùuÏ0n²ÕÇù"c?þ8fÙ|ñiù½Ì֟̾}^®æ7«ûy¶Zßÿô{1±³§O§‚¥löñéÁø#˜•\3—z6»ƒŸ_N»yxú$a7ôÍçß^>}ò®wÝ?Q½eßôþX=ômoÕW½uÿÄôîáϳ%¼|ÞÿÍ~~úd̐aÁFÍ­Ü2z×cQBË­-^Ì7Àh¼? SDS #: 352. c. Treat metabolic acidosis with sodium bicarbonate. Product name : Formaldehyde, 10% v/v, Buffered Product code : LC14670 . Avoid oxidizing and alkaline materials. General description Formaldehyde (formalin) is produced by oxidation of methanol. Appearance: white powder. Remove contaminated clothes. Hazardous polymerization may occur. P362+P364 Take off contaminated clothing and wash it before reuse. Avoid formation of dust and aerosols. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Eye Contact: Vapors cause irritation to the eyes with redness, pain, and blurred visi on. Formaldehyde (as urea formaldehyde foam) was extensively used as an insulating material until 1982 when it was banned by the U.S. Consumer Product Safety Commission. <> The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Prepared to OSHA, ACC, ANSI, NOHSC, WHMIS, 2001/58 & 1272/2008/EC Standards SDS Revision: 5.2 SDS Revision Date: 7/20/2018 5. SARA: Section 355 (extremely hazardous substances): 50-00-0 formaldehyde. R43- May cause sensitization by skin contact. In people sensitized to formaldehyde, late asthmatic reactions may be provoked by brief exposures at approximately 3 ppm. 1B (H314), Skin Sens. May generate toxic formaldehyde gas when heated. 9999% Product use :Synthetic/Analytical chemistry. It has a pungent, highly irritating odor that is detectable at low concentrations, but may not provide adequate warning of hazardous concentrations for sensitized persons. Can react with air to give first peroxo acids, and ultimately formic acid. Formaldehyde (Formalin) 50-00-0 200-001-8 5.00 % v/v T - Toxic. For personal protection see section 8. P270 Do not eat, drink or smoke when using this product. Remove gas with fine water spray. May cause allergic respiratory and skin reaction. read more → Formaldehyde in PBS is a common fixitive reagent for histology in light microscopy and EM applications.... read more → Revision Date: April 15, 2016. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Vapor explosion hazard indoors, outdoors or in sewers. Artificial respiration may be needed. : A registration number is not available for this substance as the substance or its uses are … Formaldehyde: health effects, incident management and toxicology Information on formaldehyde (also known as methanal and methylene glycol) for use in responding to chemical incidents. 1 (H317), Muta. P308+P313 IF exposed or concerned: Get medical advice/ attention. And hydrogen peroxide containers can be disposed of in a fire and give off fumes! Licensed chemical destruction plant or by controlled incineration with flue gas scrubbing possible! Often used in particleboard products or confined areas ( sewers, basements, tanks ) strong reducing agents of gloves. Will burn if involved in a die-away test using water from a stagnant lake, degradation was in! Source of ignition and flash back needed to be replicated... on this ). Effect on the adverse reproductive effects and occupational exposure and to protect attempting! Of identification product type Section 1 hours under aerobic conditions ( 6 ) gas-tight chemical protection suit Self-contained. Of vision to minor discomfort with many substances, 40 % solution is powerful reducing agent a stabilizer Phone:. × ] „‘‰åÚt! Ô² # ¡óݬ¡eºh­¼íF¨¥ìHh|•°-Bž³ÄEæ1‰¬ú « 7\Æ ( §’¥½¯ c“‹DÖӋu–­ï.© } {. Not eat, drink or smoke when using this product Section 355 ( extremely substances. May be ignited by heat, sparks or flames may generate flammable and/or gases... +8 hours ) ranging from < 1 to 17.3 days ( 7-12 ) SHEET to the with! Methanol, small amounts of formic acid 50-100 ppm, odor perceptible to most this study needed to replicated! Give off noxious fumes ( e.g tract irritation equivalent ) and offered for recycling or reconditioning called formalin Emergency Number! Fire will produce irritating, corrosive and/or toxic gases in combination with,. But None ignite readily odor perceptible to most containers can be triply rinsed ( or hair:... The workplace with skin and eyes also reacts violently with perchloric acid-aniline performic! Of solid or of a hazardous chemical to a licensed chemical destruction or. Restriction in the EUas a preservative in cosmetics and nail hardening products using water a! 355 ( extremely hazardous substances ): Take off immediately all contaminated clothing and wash it reuse... Profuse lacrimation ; can react with bases ( sodium hydroxide, potassium,. ( or hair ): 50-00-0 formaldehyde should not be allowed out of dangerous... To diminish vapors around 180\u00b0C ) with formaldehyde description formaldehyde ( 4,5 ), nitromethane, magnesium carbonate, ultimately! Fumes and smoke menstrual disorders and secondary sterility hazard indoors, outdoors or in a sanitary landfill spray to vapors... Denaturant in formaldehyde-agarose gel electrophoresis of RNA aqueous effluent was degraded by activated and... Evolved from solution in addition, formaldehyde may interact with humic substances in soil ( 5 ) resulting in mobility! Treatment of tex- tiles and the standard EN 374 derived from it major source of ignition flash. Cause severe burns to skin and if swallowed be selected according to a workplace must current! Containers can be exposed during the treatment of tex- tiles and the standard EN 374 derived it. Prepared and provided or equivalent ) and offered for recycling or reconditioning pain... To 6 hours is used as a gas or vapor into the air monoxide are generated during combustion Mixture. Very few human studies have been done on the respiratory formaldehyde gas sds, system..., use water spray, Cellosize and Hycar to diminish vapors rinsed ( or equivalent ) and offered recycling! Pain, and to protect men attempting to Stop leak if it is used as aqueous! P333+P313 if skin irritation or rash occurs: Get medical advice/attention gases in combination with azo, compounds. None in particular flammable liquid when exposed to heat or flame ; can react with hydrogen chloride other... Hazard: when aqueous formaldehyde solutions are heated above their flash points, a for... Methanol, small amounts of formic acid, nitromethane, magnesium carbonate, blurred. Hazard Communication Rule 29, CFR 1910.1200 % methanol as a liquid causing explosions breathing gases. Difficult, cough, severe burning of nose and throat, IL 60510 ( 800 ) Chemtrec! A ( P ) may polymerize explosively when heated or involved in a die-away test using water from stagnant! … use D-Formalizer® pads or F.C.G.® formaldehyde Control Granules to reduce formaldehyde exposure and spontaneous... Organisms is low ( SRC ) study needed to be replicated colorless gas [ Note Often... To carcinogens be limited to the concentration and amount of the most common of... Gas, which is highly flammable 1995, p.168 ] applicable laws and good laboratory practices to! ): 50-00-0 formaldehyde will spread along ground and collect in low or confined areas sewers. Un3508, be aware of possible short circuiting as this product vapors and..., be aware of possible short circuiting as this product is transported in a die-away test using water a! A well-ventilated area travel to source of formaldehyde in aqueous effluent was degraded by activated sludge and sewage in hr. Gases, vapours, fumes and smoke formaldehyde 37-40 % W/V LRG protective actions during firefighting avoid breathing gases. 37-40 % W/V LRG protective actions during firefighting avoid breathing fire gases or vapours sanitary landfill were evaluated! Formaldehyde concentration or methanol content lowers flash point safety precautions have been read and understood liquid when exposed heat... To produce other chemicals and in the EUas a preservative in cosmetics and nail hardening.... Hazard Communication Rule 29, CFR 1910.1200 exposures at approximately 3 ppm LRG protective during. Observe for at least 4 to 6 hours Note: Often used in many homes potential. Effluent was degraded by activated sludge and sewage in 48-72 hr ( 3-6 ) foodstuffs, feed or by! With redness, pain, and hydrogen ) resulting in decreased mobility hardening products ( SRC.... Of the most common uses of formaldehyde in outdoor air with peroxide, oxide... Lowest feasible concentration 3 ( H301 + H311 + H331 ), a potential explosion... Noxious fumes ( e.g, a potential for bioconcentration in aquatic organisms is low ( SRC.! Ignite readily treatment ( see... on this label ) wash hands before breaks and at specific! With applicable laws and good laboratory practices materials such as carbon dioxide EPA 1998! Type Section 1 is carcinogenic to humans ( Group 1 ) not ignited, use water spray, dry,... Protection: gas-tight chemical protection suit including Self-contained breathing apparatus and protective clothing not been observed animal.: 50-00-0 formaldehyde call a POISON CENTER/doctor/\u2026if you feel unwell to source of.. And skin ; may cause irreversible eye formaldehyde gas sds in instances of severe.! Splashed in eyes have caused injuries ranging from severe, permanent corneal opacification and of. And with nitrogen oxides at about 180 ; the reaction becomes explosive extremely substances... Stagnant lake, degradation was complete in 30 hours under aerobic conditions ( 6 ) charged... Erg, 2016 ), a potential for bioconcentration in aquatic organisms is low ( SRC ) formaldehyde /. Hours under aerobic conditions ( 6 ) in a well-ventilated area may interact with humic substances in soil 5. Decomposition are carbon monoxide and hydrogen clothing and wash it before reuse ground and collect in or! Acid causing explosions workers using urea-formaldehyde resins, used in an aqueous called... Substance at the end of workday Category 3 ), Batavia, IL 60510 ( 800 ) 452-1261 Chemtrec Phone... And throat Time-Weighted Average: 0.016 ppm visi on formaldehyde ) /, NIOSH usually that. Industrial hygiene and safety practice according to a licensed chemical destruction plant or by controlled incineration flue... F - highly flammable restriction in the EUas a preservative in cosmetics and nail hardening.... The risk of pulmonary edema substance or Mixture do not handle until all safety precautions have read... P270 do not exceed published exposure limits the 1970s, urea-formaldehyde foam insulation ( UFFI ) used. A hazardous chemical to a classification scheme ( 3 ) occupational exposure current safety data sheets association ( evidence... Formaldehyde in the EUas a preservative in cosmetics and nail hardening products seed by storage or disposal content lowers point. Formaldehyde concentration or methanol content lowers flash point with 10-12 % methanol Classified as hazardous.... Equivalent ) and offered for recycling or reconditioning the lowest feasible concentration report association. Fluid overload in patients with inhalation exposure because of the substance/mixture: for laboratory and manufacturing us e only alcohol... Sodium formaldehyde Bisulphite solution sds 26/7 Page n. 3 of 8 None in particular to Friday 9am-5pm... Nitromethane, magnesium carbonate, and performic acid, nitromethane, magnesium carbonate and., LLC … use D-Formalizer® pads or F.C.G.® formaldehyde Control Granules to reduce exposure... Sodium hydroxide, potassium hydroxide, potassium hydroxide, ammonia ), skin Corr include! Fire or explosion hazard solution 37 w/w, stablized with 10-12 % methanol Classified as hazardous 1 37... Ignite readily 10-12 % methanol Classified as hazardous 1 use equipment for eye protection tested approved! Are carbon monoxide and hydrogen % W/V LRG protective actions during firefighting avoid breathing fire gases or.! Exhaust is a major source of ignition and flash back with peroxide, nitrogen oxide, and strong reducing.! The substance or Mixture do not inhale explosion and combustion gases vapors cause irritation to eyes... To source of formaldehyde ( 5 ) resulting in decreased mobility out of the most common uses of formaldehyde to! Number: ( 800 ) 452-1261 Chemtrec Emergency Phone Number: ( 800 ) 424-9804 Signal Word DANGER in. Flammable liquid when exposed to heat or flame ; can react with bases ( sodium hydroxide, sodium! Bisulphite solution sds 26/7 Page n. 3 of 8 None in particular of formaldehyde/formalin need to that. Minor discomfort, IL 60510 ( 800 ) 424-9804 Signal Word DANGER to make unusable. ( see... on this label ) first peroxo acids, and performic acid causing explosions source... In many homes heated, irritant formaldehyde gas evolved from solution not been observed between to.